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Current issue   Ukr. J. Phys. 2016, Vol. 61, N 2, p.107-116
doi:10.15407/ujpe61.02.0107    Paper

Kutsyk A.M., Obukhovsky V.V.

Taras Shevchenko National University of Kyiv, Faculty of Physics
(64, Volodymyrs’ka Str., Kyiv 01033, Ukraine; e-mail: a.m.kutsyk@gmail.com, vobukhovsky@yandex.ru)

Nonlinear Diffusion in the Liquid Solution of Diethyl Ether with Chloroform

Section: Soft matter
Original Author's Text: Ukrainian

Abstract: Nonlinear diffusion in the binary liquid solution of diethyl ether with chloroform accompanied by a complex formation reaction has been considered. It is shown that the account for the possibility of the [A1B1] complex formation can explain the nonlinear concentration dependence of the mutual diffusion coefficient. The calculation results are compared with the results of other approaches. A nonlinear modification of Fick’s law was demonstrated to provide the best description of experimental results, i.e. it gives the smallest average relative deviation.

Key words: nonlinear diffusion, mutual diffusion coefficient, complex formation, diethyl ether, chloroform.

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