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Current issue    Ukr. J. Phys. 2015, Vol. 60, N 4, p.356-361
https://doi.org/10.15407/ujpe60.04.0356    Paper

Tolochko A.1, Teselko P.2, Lyashchova A.1, Fedorenko D.1, Klimusheva G.1, Mirnaya T.3, Asaula V.3

1 Institute of Physics, Nat. Acad. of Sci. of Ukraine
(46, Nauky Ave., Kyiv 03680, Ukraine; e-mail: klimush@iop.kiev.ua)
2 Taras Shevchenko National University of Kyiv
(2, Academician Glushkov Ave., Kyiv 03022, Ukraine)
3 Vernadskyi Institute of General and Inorganic Chemistry, Nat. Acad. of Sci. of Ukraine
(32/34, Academician Palladin Ave., Kyiv 03142, Ukraine)

Structure and Spectral Properties of New Composites Based on Metal Alkanoates with Gold Nanoparticles

Section: Nanosystems
Language: Ukrainian

Abstract: New composites with gold nanoparticles (NPs) have been chemically synthesized in the liquid crystal phase of cadmium and cobalt octanoates. Polymorphism and basic structural characteristics of metal alkanoates and nanocomposites (metal alkanoates with gold NPs) are analyzed, by using the small-angle X-ray scattering method. The structural parameters of gold NPs (their form and dimensions) are estimated by the X-ray spectroscopy and transmission electron microscopy techniques. The dependences of the NP absorption spectra on the spectral properties of cadmium- and cobalt-octanoate matrices are analyzed.

Key words: nanocomposites, gold nanoparticles, metal alkanoates, absorption spectra, small-angle X-ray scattering.


  1. L.W. Tutt and A. Kost, Nature 356, 225 (1992). CrossRef
  2. C. Min, P. Wang, C. Chen, Y. Deng, Y. Lu, H. Ming, T. Ning, Y. Zhou, and G. Yang, Opt. Lett. 33, 869 (2008). CrossRef
  3. D. Arivuoli, Pramana J. Phys. 57, 871 (2001).
  4. A.L. Stepanov, Rev. Adv. Mater. Sci. 27, 115 (2011).
  5. R.A. Ganeev and A I. Ryasnyansky, Appl. Phys. B 84, 295 (2006). CrossRef
  6. P. Sudheesh and K. Chandrasekharan, Solid State Commun. 152, 268 (2012). CrossRef
  7. K.S. Merza, H.D. Al-Attabi, Z.M. Abbas, and H.A. Yusr, Green Sustain. Chem. 2, 26 (2012). CrossRef
  8. M.R. Johan, L.C. Chong, and N.A. Hamizi, Int. J. Electrochem. Sci. 7, 4567 (2012).
  9. H. Qi and T. Hegmann, Liq. Cryst. Today 20, 102 (2011). CrossRef
  10. S. Qu, C. Zhao X. Jiang, G. Fang, Y. Gao, H. Zeng, Y. Song, J. Qiu, C. Zhu, and K. Hirao, Chem. Phys. Lett. 368, 352 (2003). CrossRef
  11. T.A. Mirnaya, G.G. Yaremchuk, N.A. Leonova, V.N. Asaula, and S.V. Volkov, Patent UA 86660 (Ukraine), Publ. 10.01.2014.
  12. Yu.A. Garbovskiy, A.V. Gridyakina, G.V. Klimusheva, A.S. Tolochko, I.I. Tokmenko, and T.A. Mirnaya, Liq. Cryst. 37, 1411 (2010). CrossRef
  13. D.I. Svergun, J. Appl. Cryst. 24, 485 (1991). CrossRef
  14. P. Konarev, M. Petoukhov, V. Volkov, and D. Svergun, J. Appl. Cryst. 39, 277 (2006). CrossRef
  15. T.A. Mirnaya and S.V. Volkov, in Green Industrial Application of Ionic Liquids, edited by R.D. Rogers, K.R. Seddon, and S.V. Volkov (Kluwer Acad. Publ., London, 2002).
  16. V. Amendola and M. Meneghetti, J. Phys. Chem. C 113, 4277 (2009). CrossRef
  17. S.V. Volkov and K.B. Yatsimirskii, Spectroscopy of Molten Salts (Naukova Dumka, Kyiv, 1977) (in Russian).