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Current issue   Ukr. J. Phys. 2015, Vol. 60, N 11, p.1108-1114
https://doi.org/10.15407/ujpe60.11.1108    Paper

Bulavin L.A.1, Gotsulskiy V.Ya.1, Malomuzh N.P.2, Stiranets M.V.2

1 Taras Shevchenko National University of Kyiv, Faculty of Physics
(4, Academician Glushkov Ave., Kyiv 03127, Ukraine; e-mail: vygot@onu.edu.ua)
2 I.I. Mechnikov National University of Odessa, Faculty of Physics
(42, Pasteur Str., Odesa 65026, Ukraine)

Refractometry of Water–Ethanol Solutions near Their Contraction Point

Section: Soft matter
Original Author's Text: Ukrainian

Abstract: The concentration dependences of the refractive index in aqueous ethanol solutions at equilibrium have been studied experimentally. Special attention was paid to their behavior in a vicinity of the peculiar point defined as the intersection point of the concentration dependences of the contraction measured at different temperatures or as a point, at which the intensity of molecular light scattering has a maximum. The refractive index is found to noticeably deviate from its reference values in a vicinity of the peculiar point, 0.05 < x < 0.1 (x is the mole fraction of ethanol). This effect reflects the fact that the equilibrium properties of the solutions concerned are established only during a few weeks. Arguments that the system becomes microinhomogeneous in this concentration interval are presented

Key words: water-alcohol solutions, refractive index, microinhomogeneous structure.


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